C-2-symmetric bissulfoximines in palladium-catalyzed allylic alkylations

Citation
C. Bolm et al., C-2-symmetric bissulfoximines in palladium-catalyzed allylic alkylations, SYNLETT, (12), 2001, pp. 1878-1880
Citations number
33
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
0936-5214 → ACNP
Issue
12
Year of publication
2001
Pages
1878 - 1880
Database
ISI
SICI code
0936-5214(200112):12<1878:CBIPAA>2.0.ZU;2-D
Abstract
C-2-Symmetric bissulfoximines 2 have been used as chiral ligands in palladi um-catalyzed asymmetric allylic alkylations. With 2c enantioselectivities o f up to 98% ee have been achieved in the reaction of 1,3-diphenylpropenyl a cetate with malonates as nucleophiles.