Photodissociation of allyl cyanide at 193 nm

Citation
Cy. Oh et al., Photodissociation of allyl cyanide at 193 nm, CHEM P LETT, 342(1-2), 2001, pp. 27-30
Citations number
16
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
0009-2614 → ACNP
Volume
342
Issue
1-2
Year of publication
2001
Pages
27 - 30
Database
ISI
SICI code
0009-2614(20010706)342:1-2<27:POACA1>2.0.ZU;2-Y
Abstract
Photodissociation dynamics of allyl cyanide at 193 nm has been investigated by measuring laser-induced fluorescence spectra of CN fragments. From the spectra, rotational and vibrational energy distributions of CN have been ob tained. The measured average rotational energy is 1080, 900 and 760 cm(-1) for v" = 0, 1,2, respectively, and the fraction of the vibrational populati on is 0.70/0.24/0.06 for v" = 0/1/2. The measured distributions are well re presented by statistical prior calculations, from which the detailed dissoc iation dynamics is discussed. (C) 2001 Elsevier Science B.V. All rights res erved.