Synthesis, crystal structure and electrical conductivity of [bmim][Ni(dmit)(2)](3) (bmim=1-butyl-3-methylimidazolium, dmit=1,3-dithiol-2-thione-4,5-dithiolate)

Citation
W. Xu et al., Synthesis, crystal structure and electrical conductivity of [bmim][Ni(dmit)(2)](3) (bmim=1-butyl-3-methylimidazolium, dmit=1,3-dithiol-2-thione-4,5-dithiolate), SYNTH METAL, 122(2), 2001, pp. 409-412
Citations number
18
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
0379-6779 → ACNP
Volume
122
Issue
2
Year of publication
2001
Pages
409 - 412
Database
ISI
SICI code
0379-6779(20010601)122:2<409:SCSAEC>2.0.ZU;2-M
Abstract
A new complex [bmim][Ni(dmit)(2)](3) has been prepared, and its crystal str ucture and electrical conductivity where determined and measured. Crystallo graphic parameters for C26H15N2S30Ni3: triclinic system; space group: P-1; a = 12.760(3), b=19.441(4), c = 11.670(2) Angstrom; a = 102.00(3), beta = 1 17.10(3), gamma = 95.06(3)degrees; Z = 2, R = 0.0579 (I > 2 sigma (I)). The conductivity of this salt at room temperature is 1.7 x 10(-2) S cm(-1) and it shows semiconduction in the temperature range of 110-290 K. (C) 2001 El sevier Science B.V. All rights reserved.