A molybdenum complex with 4,7-diphenyl-1,10-phenanthroline

Citation
Xj. Xie et al., A molybdenum complex with 4,7-diphenyl-1,10-phenanthroline, ACT CRYST C, 57, 2001, pp. 696-697
Citations number
9
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
0108-2701 → ACNP
Volume
57
Year of publication
2001
Part
6
Pages
696 - 697
Database
ISI
SICI code
0108-2701(200106)57:<696:AMCW4>2.0.ZU;2-K
Abstract
In the title compound, tetracarbonyl(4,7-diphenyl-1,10-phenanthroline-N,N') molybdenum(0), [Mo(C24H16N2)(CO)(4)], the Mo-atom coordination is distorted octahedral, with two CO groups cis to each other, but each trans to an N a tom of the 4,7-diphenyl-1,10-phenanthroline (dpphen) ligand, and with the o ther two CO groups trans to each other and on the axis position. The comple x has better solubility than [Mo(phen)(CO)(4)], where phen is 1,10-phenanth roline.