Synthesis and properties of optically active 1,1 ': 5 ',1 '': 5 '',1 '''-quaternaphthalene-2,2 ',6 ',2 '',6 '',2 '''-hexol (QUANOL)

Citation
T. Sugimura et al., Synthesis and properties of optically active 1,1 ': 5 ',1 '': 5 '',1 '''-quaternaphthalene-2,2 ',6 ',2 '',6 '',2 '''-hexol (QUANOL), ENANTIOMER, 6(1), 2001, pp. 35-42
Citations number
19
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
ENANTIOMER
ISSN journal
1024-2430 → ACNP
Volume
6
Issue
1
Year of publication
2001
Pages
35 - 42
Database
ISI
SICI code
1024-2430(2001)6:1<35:SAPOOA>2.0.ZU;2-0
Abstract
Optically active (R,R,R)- and (R,S,R)-1,1':5',1" :5",1"'-quaternaphthalene- 2,2',6',2",6",2" '-hexol (QUANOL) were prepared from (R)-BINOL in five step s. The CD spectrum of (R,R,R)-QUANOL showed a larger A value than those of (R)-BINOL and (R,S,R)-QUANOL, but additivity of the axial chiralities in th e A value was not observed. Other basic properties for the use of QUANOL as a chiral ligand are also reported.