Structural change of a hydrogenated carbon film upon heating

Citation
Zj. Zhang et al., Structural change of a hydrogenated carbon film upon heating, J PHYS-COND, 13(22), 2001, pp. L475-L481
Citations number
12
Language
INGLESE
art.tipo
Letter
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF PHYSICS-CONDENSED MATTER
ISSN journal
0953-8984 → ACNP
Volume
13
Issue
22
Year of publication
2001
Pages
L475 - L481
Database
ISI
SICI code
0953-8984(20010604)13:22<L475:SCOAHC>2.0.ZU;2-I
Abstract
We report, in this letter, the thermal annealing behaviour of a metastable crystalline hydrogenated carbon film prepared by plasma-enhanced chemical v apour deposition. X-ray diffraction, micro-Raman and Fourier-transform infr ared (FTIR) spectrometers were used to monitor the structural transition in the film upon heating in the air. The resultant change in the film propert ies, e.g., the mass density and optical band gap, was investigated by specu lar x-ray reflectivity measurement and by optical reflectivity measurement in the visible and ultraviolet range. It was found that the structural chan ge as well as the resultant change, in the film properties, is closely rela ted to the release process of the bonded hydrogen in the film at elevated t emperatures.