Direct conversion of alpha,beta-unsaturated nitriles into cyanohydrins using Mn(dpm)(3) catalyst, dioxygen and phenylsilane

Citation
P. Magnus et al., Direct conversion of alpha,beta-unsaturated nitriles into cyanohydrins using Mn(dpm)(3) catalyst, dioxygen and phenylsilane, TETRAHEDR L, 42(25), 2001, pp. 4127-4129
Citations number
13
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
0040-4039 → ACNP
Volume
42
Issue
25
Year of publication
2001
Pages
4127 - 4129
Database
ISI
SICI code
0040-4039(20010618)42:25<4127:DCOANI>2.0.ZU;2-3
Abstract
Treatment of alpha,beta -unsaturated nitriles with Mn(dpm)(3) (3 mol%), PhS iH3 in isopropyl alcohol in the presence of oxygen resulted in reduction an d alpha- and beta -hydroxylation. (C) 2001 Elsevier Science Ltd. All rights reserved.