Vibrational spectra study of the isomerizational reaction of nitryl hydride

Citation
Zy. Zhou et al., Vibrational spectra study of the isomerizational reaction of nitryl hydride, SPECT ACT A, 57(13), 2001, pp. 2555-2560
Citations number
8
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
ISSN journal
1386-1425 → ACNP
Volume
57
Issue
13
Year of publication
2001
Pages
2555 - 2560
Database
ISI
SICI code
1386-1425(200111)57:13<2555:VSSOTI>2.0.ZU;2-9
Abstract
The vibrational spectral study of the isomerization reaction of nitryl hydr ide is presented in this paper. The isomerizational reaction includes old b ond rupture, new bond formation and electronic transfer in the intramolecul e. For the isomerizational reaction, the vibrational modes, the vibrational frequencies and the force constants of the reactant, the transition states and product are analyzed. The relationship and the change among them can c onfirm the rupture of bond, the formation of bond and the process of electr on transfer, (C) 2001 Elsevier Science B.V. All rights reserved.