The spin-polarized light-emitting diode (spin-LED) is a very effective tool
for accurately quantifying electrical spin injection in a model independen
t manner. We resolve and identify various components which occur in the ele
ctroluminescence (EL) spectra of GaAs quantum-well-based spin-LEDs, and exa
mine the circular polarization of each. While a number of components exhibi
t significant circular polarization, the values do not necessarily reflect
the electrical spin injection efficiency. We show that a reliable measure o
f spin injection efficiency can be obtained only if one takes care to spect
roscopically resolve and accurately identify the free exciton or free carri
er components of the EL spectrum, and exclude other components. (C) 2001 Am
erican Institute of Physics.