Rh-Pt heterobimetallic complexes with unsymmetrically bridging organosilylligands: Crystal structure and dynamic behavior in solution

Citation
M. Tanabe et K. Osakada, Rh-Pt heterobimetallic complexes with unsymmetrically bridging organosilylligands: Crystal structure and dynamic behavior in solution, CHEM LETT, (10), 2001, pp. 962-963
Citations number
14
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
0366-7022 → ACNP
Issue
10
Year of publication
2001
Pages
962 - 963
Database
ISI
SICI code
0366-7022(20011005):10<962:RHCWUB>2.0.ZU;2-N
Abstract
Pt[SiH(C6H4F-4)(2)}(2)(PMe3)(2) reacts with Rh (I) complexes to afford new Rh-Pt heterobimetallic complexes with bridging hydrido and diarylsilyl liga nds. These complexes were characterized by X-ray crystallography. The NMR s pectra exhibit dynamic behavior of hydrogen atoms and three PMe3 ligands bo nded to Rh center in solution.