Pt[SiH(C6H4F-4)(2)}(2)(PMe3)(2) reacts with Rh (I) complexes to afford new
Rh-Pt heterobimetallic complexes with bridging hydrido and diarylsilyl liga
nds. These complexes were characterized by X-ray crystallography. The NMR s
pectra exhibit dynamic behavior of hydrogen atoms and three PMe3 ligands bo
nded to Rh center in solution.