The first 1,3-digermyla-2-nickela-carboranylene and the Ni-catalyzed double germylation of unsaturated organic substrates

Citation
J. Lee et al., The first 1,3-digermyla-2-nickela-carboranylene and the Ni-catalyzed double germylation of unsaturated organic substrates, CHEM COMMUN, (18), 2001, pp. 1730-1731
Citations number
14
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
1359-7345 → ACNP
Issue
18
Year of publication
2001
Pages
1730 - 1731
Database
ISI
SICI code
1359-7345(20010921):18<1730:TF1ATN>2.0.ZU;2-T
Abstract
The reaction of o-bis(dimethylgermyl)carborane with Ni(PEt3)(4) in pentane affords the reactive intermediate, [o-(GeMe2)(2)C2B10H10]Ni(PEt3)(2) 2: the facile double germylation of unsaturated organic substrates catalyzed by 2 is reported.