Preparation of masked 2,2-difluoro-1,3-diols and 2,2-difluoro-1,3,4-butanetriol via photochemical and thermal addition of oxygenated radicals to 2,2-difluorovinyl carbamate

Citation
T. Okano et al., Preparation of masked 2,2-difluoro-1,3-diols and 2,2-difluoro-1,3,4-butanetriol via photochemical and thermal addition of oxygenated radicals to 2,2-difluorovinyl carbamate, SYNLETT, (9), 2001, pp. 1449-1451
Citations number
17
Language
INGLESE
art.tipo
Letter
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNLETT
ISSN journal
0936-5214 → ACNP
Issue
9
Year of publication
2001
Pages
1449 - 1451
Database
ISI
SICI code
0936-5214(200109):9<1449:POM2A2>2.0.ZU;2-P
Abstract
Photoreaction of difluorovinyl carbamate in some alcohols except for methan ol gave radical addition products as masked forms of 2,2-difluoro-1,3-diols . 1,3-Dioxolane also gave a radical product in thermal radical reaction ini tiated bynzoyl peroxide. Radical product of 2,2-Dimethyl-1,3-dioxolane was converted into masked 2,2-difluoro-1,3-propanediol.