High-refractive-index thin films prepared from aminoalkoxysilane-capped pyromellitic dianhydride-titania hybrid materials

Citation
Cc. Chang et Wc. Chen, High-refractive-index thin films prepared from aminoalkoxysilane-capped pyromellitic dianhydride-titania hybrid materials, J POL SC PC, 39(19), 2001, pp. 3419-3427
Citations number
25
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
ISSN journal
0887-624X → ACNP
Volume
39
Issue
19
Year of publication
2001
Pages
3419 - 3427
Database
ISI
SICI code
0887-624X(20011001)39:19<3419:HTFPFA>2.0.ZU;2-X
Abstract
High-refractive-index aminoalkoxysilane-capped pyromellitic dianhydride (PM DA)-titania hybrid optical thin films (TP0-TP8) were synthesized and charac terized in this study. They were prepared with PMDA, aminopropyltrimethoxys ilane, and titanium(IV) isopropoxide via a sol-gel process followed by spin coating and multistep baking. Through adjustments in the concentration and reaction time, the inorganic content in the hybrid thin films could be as high as 59.1 wt %. The Fourier transform infrared results indicated success ful bonding between the organic and inorganic moieties. However, residues o f the chelating ligands were found in the hybrids with high titania content s, affecting their thermal and optical properties. Field emission scanning electron microscopy results suggested a nanosized domain of the titania seg ment in the hybrid materials TP0-TP8. An atomic force microscopy study sugg ested that the hybrid thin films had good planarization. The dispersions of the refractive index and extinction coefficient in the wavelength range 19 0-900 nm were studied. The refractive indices of the prepared hybrid thin f ilms at 633 run increased linearly from 1.567 to 1.780 with increasing tita nia content. However, the Abbe numbers of the hybrid thin films showed an o pposite trend. Excellent optical transparence was obtained in the visible r egion for the prepared hybrid thin films. (C) 2001 John Wiley & Sons, Inc.