Synthesis and reactions of (1,1 '-Bi-1H-phosphirene)iron complexes - Crystal structure of a bridged (1-phosphaallyl-1H-phosphirene)diiron(Fe-Fe) complex

Citation
J. Simon et al., Synthesis and reactions of (1,1 '-Bi-1H-phosphirene)iron complexes - Crystal structure of a bridged (1-phosphaallyl-1H-phosphirene)diiron(Fe-Fe) complex, EUR J INORG, (8), 2001, pp. 2067-2073
Citations number
41
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
1434-1948 → ACNP
Issue
8
Year of publication
2001
Pages
2067 - 2073
Database
ISI
SICI code
1434-1948(200108):8<2067:SARO('>2.0.ZU;2-K
Abstract
The reactions of 1-chloro-1H-phosphirenes 5 with disodium tetracarbonlyferr ate lead to the selective formation of the mono complexed bi-1H-phosphirene s 7, which are converted into the doubly complexed species 9 upon treatment with di-iron nonacarbonyl, Photochemical opening of one of the two three-m embered ring systems in 9 furnishes the bridged complexes 10 containing pho sphirene and phosphaallyl units together with an iron-iron sigma -bond.