2,2 ': 6 ',2 ''-Terpyridine metal complexes as building blocks for extended functional metallo-supramolecular assemblies and polymers

Citation
Us. Schubert et al., 2,2 ': 6 ',2 ''-Terpyridine metal complexes as building blocks for extended functional metallo-supramolecular assemblies and polymers, SYNTH METAL, 121(1-3), 2001, pp. 1249-1252
Citations number
32
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SYNTHETIC METALS
ISSN journal
0379-6779 → ACNP
Volume
121
Issue
1-3
Year of publication
2001
Pages
1249 - 1252
Database
ISI
SICI code
0379-6779(20010315)121:1-3<1249:2'6''M>2.0.ZU;2-#
Abstract
2,2 ' :6 ' ,2 " -Terpyridine ligands were used for the preparation of vario us transition metal complexes including Zn(II), Cd(II), Cu(II), Co(II), Ni( II), Mn(II), Hg(II) and Ru(II) with hexafluorophosphate counterions, In add ition to standard characterization methods the spectroscopic properties of the complexes were investigated and the crystallographic structure solved. The ruthenium(II) complex revealed the most interesting photochemical prope rties. First extended systems combining copolymers or fullerene units and t erpyridine metal complexes were synthesized.