A structural model of the ferrichrome type siderophore: chiral preference induced by intramolecular hydrogen bonding networks in ferric trihydroxamate

Authors
Matsumoto, K Ozawa, T Jitsukawa, K Einaga, H Masuda, H
Citation
K. Matsumoto et al., A structural model of the ferrichrome type siderophore: chiral preference induced by intramolecular hydrogen bonding networks in ferric trihydroxamate, CHEM COMMUN, (11), 2001, pp. 978-979
Citations number
13
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
1359-7345 → ACNP
Issue
11
Year of publication
2001
Pages
978 - 979
Database
ISI
SICI code
1359-7345(2001):11<978:ASMOTF>2.0.ZU;2-M
Abstract
Tris{2-[(N-acetyl-N-hydroxy)-D-alanylamino]ethyl}amine (R-TAAE) has been sy nthesized as a chiral trihydroxamate artificial siderophore with hydrogen b onding networks, whose crystal structure of the iron(iii) complex revealed Lambda configuration induced by interstrand hydrogen bonding networks and s teric repulsion by optically active amino acid residues.