The close-knit supramolecular network of bis[(tert-butyl isocyanide)gold(I)] 1,3,4-thiadiazole-2,5-disulfide

Citation
Jdet. Wilton-ely et al., The close-knit supramolecular network of bis[(tert-butyl isocyanide)gold(I)] 1,3,4-thiadiazole-2,5-disulfide, ORGANOMETAL, 20(10), 2001, pp. 1895-1897
Citations number
17
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
0276-7333 → ACNP
Volume
20
Issue
10
Year of publication
2001
Pages
1895 - 1897
Database
ISI
SICI code
0276-7333(20010514)20:10<1895:TCSNOB>2.0.ZU;2-R
Abstract
Treatment of 2 molar equiv of ((BuNC)-Bu-t)AuCl with I equiv of the dipotas sium salt of 2,5-dimercapto-1,3,4-thiadiazole, K-2(SSS), results in the for mation of the crystalline product [((BuNC)-Bu-t)Au](2)(SSS) in addition to polymeric material. A crystallographic study reveals a complex supramolecul ar structure for the crystalline product resembling a "knitted" network con taining six independent gold centers.