A single-strand polymer of hexacoordinated zinc(II) phosphodiester complex

Citation
A. Angeloff et al., A single-strand polymer of hexacoordinated zinc(II) phosphodiester complex, J ORGMET CH, 624(1-2), 2001, pp. 58-62
Citations number
19
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022-328X → ACNP
Volume
624
Issue
1-2
Year of publication
2001
Pages
58 - 62
Database
ISI
SICI code
0022-328X(20010401)624:1-2<58:ASPOHZ>2.0.ZU;2-X
Abstract
The structure of the title compound 2, catena-poly{aqua(dimethylformamide-O )bis{mu-[bis(p-nitrophenyl)phosphato]}zinc(II) mono(dimethylformamide)}, co nsists of linear polymers in which adjacent Zn2+ cations are joined by the oxygen atoms of two bidentate bridging phosphate diester ligands 1. The met al shows an octahedral coordination geometry with the zinc connected to six O atoms, four belonging to four different surrounding phosphate groups, on e to a water molecule and one to a DMF molecule. Each single-strand is buil t-up from Zn octahedrons having alternate configuration A or A. (C) 2001 El sevier Science B.V. All rights reserved.