Crystal structure of a helix layered silicate containing tetramethylammonium ions in sodalite-like cages

Citation
T. Ikeda et al., Crystal structure of a helix layered silicate containing tetramethylammonium ions in sodalite-like cages, CHEM MATER, 13(4), 2001, pp. 1286-1295
Citations number
45
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science","Material Science & Engineering
Journal title
CHEMISTRY OF MATERIALS
ISSN journal
0897-4756 → ACNP
Volume
13
Issue
4
Year of publication
2001
Pages
1286 - 1295
Database
ISI
SICI code
0897-4756(200104)13:4<1286:CSOAHL>2.0.ZU;2-8
Abstract
The crystal structure of a helix layered silicate (HLS), [(CH3)(4)N](2)Na-2 [Si10O20(OH)(4)].5,53H(2)O, with tetramethylammonium (TMA) ions as template s was determined by ab initio structure analysis with X-ray powder diffract ion data. The HLS is orthorhombic with space group Amm2 and lattice parame ters of a = 22.8641(2) Angstrom, b = 12.5388(2) Angstrom, and c = 12.4648(2 ) Angstrom. A Q(3)-Q(4)-Q(3) silicon network with an amount-of-substance ra tio of Si/O = 1:2.4 exhibits cup-shaped cage topology with four- and six-me mbered rings. Such a cage is similar to a sodalite cage divided into two pi eces. Si-29 MAS NMR showed the silicate layer to have Q(3)- and Q(4)-types of Si atoms with a Q(3)/Q(4) ratio of ca. 4.0, which is consistent with our structural model. The framework is distorted: with Si-O bond lengths varyi ng widely. TMA ions are incorporated into the cup-shaped cage. Na+ ions and H2O molecules are also located between two silicate layers, with interlaye r distances varying alternately. Disordering of TMA ions, Na+ ions, and H2O molecules was clearly visualized in electron-density maps obtained by comb ining a maximum-entropy method and whole-pattern fitting. H2O molecules sur round Na+ ions and form hydrogen bonds with O atoms in silanol groups in th e silicate layers, by which the lattice instability due to the distorted fr amework is compensated. The present compound is regarded as a metastable ph ase, as would be expected for precursors to new types of microporous materi als with silicate frameworks such as the sodalite cage.