Synthesis of organometallic dendrimers by ligand exchange reactions: reversible bonding of dendrons to a core in transition metal acetylide dendrimers

Citation
K. Onitsuka et al., Synthesis of organometallic dendrimers by ligand exchange reactions: reversible bonding of dendrons to a core in transition metal acetylide dendrimers, CHEM COMMUN, (8), 2001, pp. 741-742
Citations number
14
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
1359-7345 → ACNP
Issue
8
Year of publication
2001
Pages
741 - 742
Database
ISI
SICI code
1359-7345(2001):8<741:SOODBL>2.0.ZU;2-8
Abstract
Ligand exchange reactions of chloride ligands on a trinuclear palladium ace tylide core with platinum acetylide dendrons having a 4-pyridyl group at a focal point result in the quantitative formation of novel organometallic de ndrimers, which easily revert to the core and the dendrons by treatment wit h Bu4NCl.