Intervention by an eta(6)-organochromium moiety switches chemoselectivity in palladium-catalyzed reactions with trialkyltin compounds

Citation
D. Prim et al., Intervention by an eta(6)-organochromium moiety switches chemoselectivity in palladium-catalyzed reactions with trialkyltin compounds, ORGANOMETAL, 20(7), 2001, pp. 1279-1281
Citations number
32
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
0276-7333 → ACNP
Volume
20
Issue
7
Year of publication
2001
Pages
1279 - 1281
Database
ISI
SICI code
0276-7333(20010402)20:7<1279:IBAEMS>2.0.ZU;2-M
Abstract
The reaction of (chloroarene)tricarbonylchromium with hexaalkylditin under palladium catalysis does not proceed by the expected Stille reaction with a ddition of an SnR3 group but, instead, affords alkylarene complexes via a p ostulated chromium-assisted alkyl migration.