Intermolecular Coulombic decay of clusters

Citation
R. Santra et al., Intermolecular Coulombic decay of clusters, J ELEC SPEC, 114, 2001, pp. 41-47
Citations number
43
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
ISSN journal
0368-2048 → ACNP
Volume
114
Year of publication
2001
Pages
41 - 47
Database
ISI
SICI code
0368-2048(200103)114:<41:ICDOC>2.0.ZU;2-G
Abstract
Following inner-valence ionization of a cluster, the system can relax by ul trafast electron emission. In contrast to Anger decay this novel process is intermolecular. It is characterized by an efficient Coulombic energy trans fer mechanism between monomers in the cluster. As an example, we present an analysis of the hydrogen fluoride trimer, based on extensive ab initio com putations. (C) 2001 Elsevier Science B.dV. All rights reserved.