Highly selective induction of metal-centered chirality in the ligand exchange reaction of planar-chiral cyclopentadienyl-ruthenium complex bearing ananchor phosphine ligand

Citation
K. Onitsuka et al., Highly selective induction of metal-centered chirality in the ligand exchange reaction of planar-chiral cyclopentadienyl-ruthenium complex bearing ananchor phosphine ligand, CHEM COMMUN, (6), 2001, pp. 521-522
Citations number
23
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
1359-7345 → ACNP
Issue
6
Year of publication
2001
Pages
521 - 522
Database
ISI
SICI code
1359-7345(2001):6<521:HSIOMC>2.0.ZU;2-6
Abstract
Treatment of planar-chiral cyclopentadienyl-phosphine ruthenium complexes w ith phosphine and phosphite induces metal-centered chirality with a high st ereoselectivity (greater than or equal to 99% de).