K. Onitsuka et al., Highly selective induction of metal-centered chirality in the ligand exchange reaction of planar-chiral cyclopentadienyl-ruthenium complex bearing ananchor phosphine ligand, CHEM COMMUN, (6), 2001, pp. 521-522
Treatment of planar-chiral cyclopentadienyl-phosphine ruthenium complexes w
ith phosphine and phosphite induces metal-centered chirality with a high st
ereoselectivity (greater than or equal to 99% de).