A simple enantioselective synthesis of (R)- and (S)-1,7-dioxaspiro[5.5]undecane via intramolecular asymmetric oxyselenenylation: a new route to optically active spiroketals

Citation
M. Uchiyama et al., A simple enantioselective synthesis of (R)- and (S)-1,7-dioxaspiro[5.5]undecane via intramolecular asymmetric oxyselenenylation: a new route to optically active spiroketals, TETRAHEDR L, 42(10), 2001, pp. 1931-1934
Citations number
25
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
0040-4039 → ACNP
Volume
42
Issue
10
Year of publication
2001
Pages
1931 - 1934
Database
ISI
SICI code
0040-4039(20010304)42:10<1931:ASESO(>2.0.ZU;2-C
Abstract
Both enantiomers of 1,7-dioxaspiro[5.5]undecane, the major pheromone compon ents of the olive fruit fly (Bactrocea oleae), have been synthesized by usi ng a new method based on the intramolecular asymmetric oxyselenenylation of 4-(3,4-dihydro-2H-pyran-6-yl)butan- 1-ol. (C) 2001 Elsevier Science Ltd. A ll rights reserved.