Synthesis and structure of the [Mn-IV(biguanide)(3)](4+) ion: the simplestsource for water-stable manganese(IV)

Citation
G. Das et al., Synthesis and structure of the [Mn-IV(biguanide)(3)](4+) ion: the simplestsource for water-stable manganese(IV), CHEM COMMUN, (4), 2001, pp. 323-324
Citations number
12
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
1359-7345 → ACNP
Issue
4
Year of publication
2001
Pages
323 - 324
Database
ISI
SICI code
1359-7345(2001):4<323:SASOT[>2.0.ZU;2-X
Abstract
Aqueous oxidation of alkaline biguanide sulfate with KMnO4 followed by crys tallisation from 2 M HNO3 yields the mononuclear [Mn(bigH)(3)](4+) ion, whi ch has been characterised crystallographically and provides an easy route t o mononuclear, water-stable manganese(iv).