We report, to our knowledge, the first polarization-resolved measurement of
the frequency dependence of both the electronic and the electrostrictive c
ontributions to the de Kerr coefficient in silica. At the acoustic resonanc
e the perpendicular polarization phase shift is a factor of 2.3 times great
er than in the parallel polarization, confirming the presence of strong ele
ctrostriction. We find good agreement between the phase-shift measurements
and theoretical models of both the polarization and frequency dependence. T
he analysis indicates the de Kerr coefficient chi ((3))(1111)(omega; omega,
0, 0) to be 1.9 x 10(-22) m(2)/V-2. From these results the electrostrictiv
e contribution to a poled-silica device near the device acoustic resonance
is expected to be r(33,Es) = 28 pm/V, over an order of magnitude greater th
an the electronic Kerr electro-optic coefficient r(33,Kerr) = 0.2 pm/V. (C)
2001 Optical Society of America OCIS codes: 190.3270, 160.2750, 160.6030,
190.0190, 230.2090.