Synthesis, structural characterization, and luminescence properties of branched palladium(II) and platinum(II) acetylide complexes

Citation
Vww. Yam et al., Synthesis, structural characterization, and luminescence properties of branched palladium(II) and platinum(II) acetylide complexes, ORGANOMETAL, 20(3), 2001, pp. 453-459
Citations number
55
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
0276-7333 → ACNP
Volume
20
Issue
3
Year of publication
2001
Pages
453 - 459
Database
ISI
SICI code
0276-7333(20010205)20:3<453:SSCALP>2.0.ZU;2-O
Abstract
Three luminescent palladium(II) and platinum(II) acetylide complexes, 1,3-[ Cl(PEt3)(2)PdC=CC6H4C=C](2)-5-[(Pr-i)(3)SiC=C]C6H3 and 1,3,5-[Cl(PEt3)(2)MC =CC6H4C=C](3)C6H3 (M = Pd or Pt), have been synthesized by the reaction of the corresponding starting complexes, trans-M(PEt3)(2)Cl-2 (M = Pd or Pt), with branched alkynyl ligands. Their crystal structures, together with thei r luminescence behavior, have been reported.