Stereoselective C,C-bond formation. Cyclizations of biradicals

Citation
B. Giese et al., Stereoselective C,C-bond formation. Cyclizations of biradicals, PUR A CHEM, 72(9), 2000, pp. 1623-1629
Citations number
8
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
PURE AND APPLIED CHEMISTRY
ISSN journal
0033-4545 → ACNP
Volume
72
Issue
9
Year of publication
2000
Pages
1623 - 1629
Database
ISI
SICI code
0033-4545(200009)72:9<1623:SCFCOB>2.0.ZU;2-R
Abstract
The formation of C,C-bonds via photolytically generated biradicals can occu r with high stereoselectivity. If triplet biradicals are involved, chiral i nduction is highly likely. Syntheses that occur only via singlet biradicals have a good chance to show a memory effect of chirality.