Electro-oxidative kinetic resolution of sec-alcohols by using an opticallyactive N-oxyl mediator

Citation
M. Kuroboshi et al., Electro-oxidative kinetic resolution of sec-alcohols by using an opticallyactive N-oxyl mediator, TETRAHEDR L, 41(42), 2000, pp. 8131-8135
Citations number
12
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
0040-4039 → ACNP
Volume
41
Issue
42
Year of publication
2000
Pages
8131 - 8135
Database
ISI
SICI code
0040-4039(20001014)41:42<8131:EKROSB>2.0.ZU;2-H
Abstract
Electro-oxidative kinetic resolution of sec-alcohols mediated with a cataly tic amount of an optically active N-oxyl was performed by use of a simple u ndivided cell under constant current conditions. The selectivity factor (S- value) increased remarkably when the reaction was performed at lower temper atures. The optically active N-oxyl was recovered and used repeatedly witho ut any change in efficiency and selectivity. (C) 2000 Elsevier Science Ltd. All rights reserved.