C-60-sensitized bis-silylation of nitrile and carbonyl compounds with disilirane

Citation
Y. Maeda et al., C-60-sensitized bis-silylation of nitrile and carbonyl compounds with disilirane, J ORGMET CH, 611(1-2), 2000, pp. 414-419
Citations number
47
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANOMETALLIC CHEMISTRY
ISSN journal
0022-328X → ACNP
Volume
611
Issue
1-2
Year of publication
2000
Pages
414 - 419
Database
ISI
SICI code
0022-328X(20001006)611:1-2<414:CBONAC>2.0.ZU;2-J
Abstract
The photochemical reaction of disilirane with unsaturated compounds such as nitrile, ketone and aldehyde in the presence of C-60 with a halogen lamp ( cutoff <400 nm) affords the corresponding adducts of disilirane and unsatur ated compounds as bis-silylated products. The experimental results by using laser hash photolysis technique confirm the formation of the adducts via a photoinduced electron transfer process between 1 and 3C(60)*. I, this bis- silylation reaction, C-60 serves as a sensitizer. (C) 2000 Elsevier Science S.A. All rights reserved.