Comparison of different di-tert-butyldimethyl-silylated cyclodextrins as chiral stationary phases in capillary gas chromatography

Citation
T. Beck et al., Comparison of different di-tert-butyldimethyl-silylated cyclodextrins as chiral stationary phases in capillary gas chromatography, HRC-J HIGH, 23(10), 2000, pp. 569-575
Citations number
26
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
HRC-JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY
ISSN journal
0935-6304 → ACNP
Volume
23
Issue
10
Year of publication
2000
Pages
569 - 575
Database
ISI
SICI code
0935-6304(200010)23:10<569:CODDCA>2.0.ZU;2-4
Abstract
Separation factors and thermodynamic data for the separation of various chi ral analytes on different di-O-tert-butyldimethyl-silylated cyclodextrin de rivatives are collected and described. Modifying the substitution pattern o f the tert-butyldimethylsilyl group in position 2 and 3 or changing from be ta- to gamma-cyclodextrin significantly affects the separation properties o f the cyclodextrin derivatives.