Spectroscopic and structural studies of the complex of [Cu-6(bpy)(10)(mu-CO3)(2)(mu-OH)(2)](ClO4)(6)center dot 4H(2)O

Authors
Xu, HT Zheng, NW Yang, RY Wu, YG Li, JM
Citation
Ht. Xu et al., Spectroscopic and structural studies of the complex of [Cu-6(bpy)(10)(mu-CO3)(2)(mu-OH)(2)](ClO4)(6)center dot 4H(2)O, SPECT ACT A, 56(11), 2000, pp. 2203-2206
Citations number
10
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
ISSN journal
1386-1425 → ACNP
Volume
56
Issue
11
Year of publication
2000
Pages
2203 - 2206
Database
ISI
SICI code
1386-1425(200010)56:11<2203:SASSOT>2.0.ZU;2-M
Abstract
The electronic absorption spectrum (diffuse reflection spectrum) of the cry stal of [Cu-6(bpy)(10)(mu-CO3)(2)(mu-OH)(2)](ClO4)6 . 4H(2)O has been measu red. The experimental results are discussed quantitatively with ligand fiel d theory and the radial wave function of non-free copper(II), and calculati on values agree well with the experimental results. The d-d absorption spec trum of a novel hexanuclear copper(II) complex was explained satisfactorily . Especially, complexity of multinuclear crystal structures determined that of spectral behaviors. It provides significant to grope spectral nature fr om coordination structures. (C) 2000 Elsevier Science B.V. All rights reser ved.