Copolymerization of 4,4 '-divinyl benzoyl peroxide with methyl methacylateand grafting of butyl acrylates onto the copolymers

Citation
Z. Li et al., Copolymerization of 4,4 '-divinyl benzoyl peroxide with methyl methacylateand grafting of butyl acrylates onto the copolymers, MACRO RAPID, 21(9), 2000, pp. 590-594
Citations number
17
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULAR RAPID COMMUNICATIONS
ISSN journal
1022-1336 → ACNP
Volume
21
Issue
9
Year of publication
2000
Pages
590 - 594
Database
ISI
SICI code
1022-1336(20000620)21:9<590:CO4'BP>2.0.ZU;2-D
Abstract
A peroxide monomer, 4,4'-divinyl benzoyl peroxide (DVBPO), was synthesized. Bulk copolymerization of DVBPO with methyl methacrylate (MMA) was initiate d by di(2-ethyl hexyl)peroxy carbonate (EHP). DSC curves and the appearance of crosslinking of the product showed that DVBPO can copolymerize with MMA . The grafting copolymerization of butyl acrylate (BA) onto the copolymer w as performed. The grafting efficiency (GE), determined by Soxhlet extractio n, was high.