Spectroscopic and structural studies of the cobalt clathrate compound [Co(No3)2(4,4 '-bipyridine)1.5]

Citation
Jm. Li et al., Spectroscopic and structural studies of the cobalt clathrate compound [Co(No3)2(4,4 '-bipyridine)1.5], SPECT LETT, 33(2), 2000, pp. 147-155
Citations number
16
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
SPECTROSCOPY LETTERS
ISSN journal
0038-7010 → ACNP
Volume
33
Issue
2
Year of publication
2000
Pages
147 - 155
Database
ISI
SICI code
0038-7010(2000)33:2<147:SASSOT>2.0.ZU;2-U
Abstract
The electronic absorption spectrum of the crystals of [Co(NO3)(2)(4,4'-bpy) (1.5)](infinity) (4,4'-bpy = 4,4'-bipyridine) was recorded at room temperat ure. Eight absorption bands appeared at about 6808,7246,8312,125184,18302,2 0709,21594 and 24389 cm(-1). The experimental results agree with the value calculated with the ligand field theory (LFT) and the radial wave function of the cion-free Cobalt(II) ion. As a result, the d-d transition spectrum o f the title complex is explained satisfactorily.