Trinuclear palladium(II) complexes with 2-hydroxy-4-methoxyacetophenone N-4-dimethylthiosemicarbazone: Synthesis, spectral studies and crystal structure of a tripalladium complex

Citation
D. Kovala-demertzi et al., Trinuclear palladium(II) complexes with 2-hydroxy-4-methoxyacetophenone N-4-dimethylthiosemicarbazone: Synthesis, spectral studies and crystal structure of a tripalladium complex, EUR J INORG, (4), 2000, pp. 727-734
Citations number
54
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
ISSN journal
1434-1948 → ACNP
Issue
4
Year of publication
2000
Pages
727 - 734
Database
ISI
SICI code
1434-1948(200004):4<727:TPCW2N>2.0.ZU;2-H
Abstract
The synthesis and spectral characterization of a new triangular, trinuclear palladium(II) complex with the dianion of 2-hydroxy-4-methoxyacetophenone N-4-dimethylthiosemicarbazone, 4MeOAp4Me(2)(2-) is reported. The X-ray crys tal structure determination of [Pd(4MeOAp4Me(2))](3). DMSO shows it to cont ain a chair-type hexagon of alternating Pd and S atoms which form a molecul ar bowl. The crystal structure of H(2)4MeOAp4Me(2) shows that it is the E i somer with respect to the imine bond of the thiosemicarbazone moiety.