[(2S,4S)-4-Hydroxymethyl-1,3-dioxan-2-yl ]-ferrocene

Citation
J. Chiffre et al., [(2S,4S)-4-Hydroxymethyl-1,3-dioxan-2-yl ]-ferrocene, ACT CRYST C, 55, 1999, pp. 2045-2047
Citations number
14
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
0108-2701 → ACNP
Volume
55
Year of publication
1999
Part
12
Pages
2045 - 2047
Database
ISI
SICI code
0108-2701(199912)55:<2045:[]>2.0.ZU;2-J
Abstract
The structure of the title complex, [Fe(C5H5)(C10H13O3)], shows the occurre nce of two stereogenic centres in the hydroxymethyl-1,3-dioxane fragment. T he S configuration found for these chiral C atoms agrees with the synthetic route. The dioxane ring has a nearly perfect chair conformation. O-H ... O hydrogen bonds result in the formation of an eight-membered ring built fro m the arrangement of four complex molecules around a fourfold axis.