Ar. Boccaccini et Ea. Olevsky, Processing of platelet-reinforced glass matrix composites: effect of inclusions on sintering anisotropy, J MATER PR, 96(1-3), 1999, pp. 92-101
The effect of rigid, i.e. non-densifying inclusions on the densification ki
netics and shrinkage anisotropy during the sintering of composite glass pow
der compacts is investigated. The experimental study was conducted on bariu
m-magnesium aluminosilicate (BMAS) glass composites containing Al2O3-platel
ets as a rigid inclusion phase. Data on axial and radial shrinkage during s
intering were obtained by using heating microscopy, which allows monitoring
the densification process without the exertion of external loads, which co
uld influence the sintering kinetics. The presence of rigid platelets retar
ded the densification of the compacts. The sintering behavior of all sample
s was anisotropic, with the degree of anisotropy varying with the progress
of sintering and with the platelet content. A comprehensive qualitative exp
lanation for the effect of rigid inclusions on sintering shrinkage anisotro
py for both intrinsically isotropic and anisotropic powder compacts is offe
red. In general, the influence of rigid inclusions on shrinkage anisotropy
can be explained on the basis of the retardation effect that inclusions hav
e on the sintering and densification kinetics of porous glass compacts. The
ideas advanced in this paper form the basis for the development of a predi
ctive theoretical model for the effect of rigid inclusions on shrinkage ani
sotropy of glass powder compacts during sintering. (C) 1999 Elsevier Scienc
e S.A. All rights reserved.