Spectroscopic and structural studies of clathrate compound of Bis(ethylenediamine)-diisothiocyanatonickel(II)-benzene

Citation
Jm. Li et al., Spectroscopic and structural studies of clathrate compound of Bis(ethylenediamine)-diisothiocyanatonickel(II)-benzene, SPECT LETT, 32(5), 1999, pp. 763-771
Citations number
13
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
SPECTROSCOPY LETTERS
ISSN journal
0038-7010 → ACNP
Volume
32
Issue
5
Year of publication
1999
Pages
763 - 771
Database
ISI
SICI code
0038-7010(1999)32:5<763:SASSOC>2.0.ZU;2-9
Abstract
The electronic absorption spectrum of the title crystal of the clathrate co mpound of [Ni(en)(2)(NCS)(2)]. C6H6 has been measured. The experimental res ults are discussed quantitatively with ligand field theory(LFT) and the rad ial wave function of non-free nickel(II) ion. The calculation values coinci de well with the experimental results. In particular, they provide signific ant correlation between the electronic absorption spectrum and the crystal structure of the compound.