Cobalt(II) complexes of 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones

Citation
Dx. West et al., Cobalt(II) complexes of 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones, TRANSIT MET, 24(5), 1999, pp. 595-599
Citations number
18
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
0340-4285 → ACNP
Volume
24
Issue
5
Year of publication
1999
Pages
595 - 599
Database
ISI
SICI code
0340-4285(199910)24:5<595:CCO4NT>2.0.ZU;2-V
Abstract
Cobalt(II) complexes of five 4-acetamidobenzaldehyde N(4)-substituted thios emicarbazones have been prepared in EtOH solution and characterized by i.r. , electronic and n.m.r. spectra, and by magnetic susceptibilities and molar conductivity measurements. The thiosemicarbazones coordinate as monoanioni c or neutral ligands via the thiosemicarbazone azomethine nitrogen and thio ne/thiolato sulfur, the latter by loss of the thioamide hydrogen, N(2)H. Th e resulting cobalt(II) complexes exhibit a varied stereochemistry.