Synthesis and structure of [2]catenated tertiary octamide and octamine

Citation
N. Watanabe et al., Synthesis and structure of [2]catenated tertiary octamide and octamine, CHEM LETT, (9), 1999, pp. 915-916
Citations number
14
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
0366-7022 → ACNP
Issue
9
Year of publication
1999
Pages
915 - 916
Database
ISI
SICI code
0366-7022(199909):9<915:SASO[T>2.0.ZU;2-B
Abstract
Treatment of [2]catenated sec, octamide (1) with methyl iodine under an alk aline condition gave the corresponding N-methylated tert. octamide(2) which was reduced to [2]catenated tert. octamine (3). The structures of 2 and 3 were studied by Xray crystal structure and H-1 NMR analyses.