Copper(II) complexes of 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones

Citation
Dx. West et al., Copper(II) complexes of 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones, TRANSIT MET, 24(4), 1999, pp. 421-424
Citations number
15
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
0340-4285 → ACNP
Volume
24
Issue
4
Year of publication
1999
Pages
421 - 424
Database
ISI
SICI code
0340-4285(199908)24:4<421:CCO4NT>2.0.ZU;2-Z
Abstract
Mononuclear and binuclear copper(II) complexes with four 4-acetamidobenzald ehyde N(4)-substituted thiosemicarbazones have been prepared in EtOH soluti on and characterized by physical and spectral methods. I.r., electronic, an d e.s.r. spectra of the complexes, as well as i.r., electronic, and n.m.r. spectra of the thiosemicarbazones, have been obtained. These thiosemicarbaz ones coordinate as anionic or neutral ligands via the thiosemicarbazone moi ety's imine nitrogen and thiolate/thione sulfur, the former on loss of the hydrazido hydrogen, N(2)H.