Spectroscopic and structural studies of clathrate compound of bis(ethylenediamine)-diisothiocyanatonickel(II)-benzene

Citation
Jm. Li et al., Spectroscopic and structural studies of clathrate compound of bis(ethylenediamine)-diisothiocyanatonickel(II)-benzene, SPECT LETT, 32(3), 1999, pp. 397-405
Citations number
11
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Spectroscopy /Instrumentation/Analytical Sciences
Journal title
SPECTROSCOPY LETTERS
ISSN journal
0038-7010 → ACNP
Volume
32
Issue
3
Year of publication
1999
Pages
397 - 405
Database
ISI
SICI code
0038-7010(1999)32:3<397:SASSOC>2.0.ZU;2-2
Abstract
The electronic absorption spectrum of the title crystal of the clathrate co mpound of [Ni(en)(2)(NCS)(2)].C6H6 has been measured. The experimental resu lts are discussed quantitatively with ligand field theory(LFT) and the radi al wave function of non-free nickel(II) ion. The calculation value coincide s well with the experimental results. In particularly, it provides signific ant correlation between the electronic absorption spectrum and the crystal structure of the compound.