[1,3-bis(pyridine-2-carboxamido)propane]-palladium(II) monohydrate and itsnickel(II) analogue

Citation
M. Tamura et al., [1,3-bis(pyridine-2-carboxamido)propane]-palladium(II) monohydrate and itsnickel(II) analogue, ACT CRYST C, 55, 1999, pp. 719-722
Citations number
14
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
0108-2701 → ACNP
Volume
55
Year of publication
1999
Part
5
Pages
719 - 722
Database
ISI
SICI code
0108-2701(19990515)55:<719:[MAI>2.0.ZU;2-M
Abstract
The title compounds, [N,N'-bis (2-pyridylcarbonyl)propane-1,3-diaminato-kap pa(4)N]palladium(II) monohydrate, [Pd(C15H14N4O2)] . H2O, and [N,N'-bis(2-p yridylcarbonyl)propane-1, 3-diaminato-kappa(4)N] nickel(II) monohydrate, [N i(C15H14N4O2)] . H2O, were investigated by means of X-ray diffraction and h igh-resolution NMR. The Pd-II and Ni-II ions have regular and distorted squ are-planar coordination geometries, respectively. Libration of the propaned iyl chains in these complexes was observed in both the crystalline and solu tion states.