Ye. Yoo et al., CHARACTERISTICS OF VOLATILE FATTY-ACIDS DEGRADATION IN AQUEOUS-SOLUTION BY THE ACTION OF ULTRASOUND, Water research, 31(6), 1997, pp. 1532-1535
Aqueous solutions of volatile fatty acids (VFAs; propionic acid, n-but
yric acid and n-valeric acid) with concentrations of about 0.9 mM were
exposed to 200 kHz ultrasound with a power of 6.0 W/cm(2) per unit vo
lume in a sonochemical reactor under ambient temperature and pressure
conditions. The concentration of VFAs decreased with irradiation time,
indicating pseudo-first-order kinetics. The rates were in the range 1
3.6-3.5 (x 10(-3)) min(-1) under argon. Saturated gas affected the deg
radation rate and the order of the rates was as follows: nitrogen less
than or equal to air < argon. Mixing effects (in the presence of othe
r VFAs) were found to have little influence upon the degradation of in
dividual VFAs. (C) 1997 Elsevier Science Ltd.