INVESTIGATING HIGHLY CROSS-LINKED MACROPOROUS RESINS FOR SOLID-PHASE SYNTHESIS

Citation
M. Hori et al., INVESTIGATING HIGHLY CROSS-LINKED MACROPOROUS RESINS FOR SOLID-PHASE SYNTHESIS, Bioorganic & medicinal chemistry letters, 8(17), 1998, pp. 2363-2368
Citations number
18
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Medicinal
ISSN journal
0960-894X
Volume
8
Issue
17
Year of publication
1998
Pages
2363 - 2368
Database
ISI
SICI code
0960-894X(1998)8:17<2363:IHCMRF>2.0.ZU;2-I
Abstract
The washing efficiencies of a chromophore and the reaction rates of a classical esterification reaction are improved with macroporous resins (MRs) relative to a classical Merrifield resin. Furthermore, Wacker-o xidation of a MR bound alkene yielded the expected methylketone produc t whereas an alkene bound to a low-crosslinked Merrifield resin gave n o product, a function of the relative permeability of each of these re sins to the aqueous solvent conditions employed. (C) 1998 Elsevier Sci ence Ltd. All rights reserved.