THE SYNTHESIS AND CRYSTAL-STRUCTURE OF NOVEL HETEROPOLY COMPLEX K3H2[GEW8MO3VO40]CENTER-DOT-4H(2)O

Citation
Qy. Wu et al., THE SYNTHESIS AND CRYSTAL-STRUCTURE OF NOVEL HETEROPOLY COMPLEX K3H2[GEW8MO3VO40]CENTER-DOT-4H(2)O, Gaodeng xuexiao huaxue xuebao, 19(6), 1998, pp. 934-937
Citations number
3
Language
CHINESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
ISSN journal
0251-0790
Volume
19
Issue
6
Year of publication
1998
Pages
934 - 937
Database
ISI
SICI code
0251-0790(1998)19:6<934:TSACON>2.0.ZU;2-Y
Abstract
K3H2 [GeW8Mo3VO40]. 4H(2)O, a novel crystal was synthesized by the ste pwise acidification and the stepwise addition oi materials, The crysta l structure was determined from single crystal X-ray diffraction at ro om temperature. The complex crystallizes in the space group C-2(monocl inic), with a=1.894 4(4) nm, b=3.292 0(7) nm, c=1.249 4(2) nm, beta=90 .25(3)degrees, V=7.792(4) nm(3), Z=6. The final discrepancy factor was R=0.063, R-w=0.067.