ELECTROCHEMICAL ASPECT OF [AMINO(CARBOXY) PHTHALOCYANINATO]COBALT(II)FOR THE EFFECT ON DECOMPOSITION OF ACETALDEHYDE - NEW-TYPE OF ODOR-REMOVER AGAINST ACETALDEHYDE INCLUDED IN TOBACCO ODOR

Citation
Y. Yamasaki et T. Yamashita, ELECTROCHEMICAL ASPECT OF [AMINO(CARBOXY) PHTHALOCYANINATO]COBALT(II)FOR THE EFFECT ON DECOMPOSITION OF ACETALDEHYDE - NEW-TYPE OF ODOR-REMOVER AGAINST ACETALDEHYDE INCLUDED IN TOBACCO ODOR, Nippon kagaku kaishi, (5), 1998, pp. 364-368
Citations number
NO
Language
GIAPPONESE
art.tipo
Article
Categorie Soggetti
Chemistry
Journal title
ISSN journal
0369-4577
Issue
5
Year of publication
1998
Pages
364 - 368
Database
ISI
SICI code
0369-4577(1998):5<364:EAO[P>2.0.ZU;2-T
Abstract
It was investigated by cyclic voltammetry that the titled [amino (carb oxy) phthalocyaninato] cobalt (II) can work more effective on the deco mposition of acetaldehyde than (polycarboxyphthalocyaninato) iron (III ) from the point of electrochemical interaction. It is already reporte d that (polycarboxyphthalocyaninato) iron (III) has catalytic activity on the decomposition of acetaldehyde as if it works like enzyme catal ase; however, phthalocyaninatoiron (III) has a crucial problem that it is easily deteriorated via mu-oxo dimer in basic solution. In additio n, from our practical experiments by the measurements of odor-decay wi th gas inspection tubes, (tetracarboxyphthalocyaninato) cobalt (II) di d not work on the decomposition of acetaldehyde. We propose in this ar ticle that the titled [amino (carboxy) phthalocyaninato] cobalt (II) c ould be a practical odor-remover against acetaldehyde included in taba cco odor.