REGIOSELECTIVE SYNTHESIS OF SEVERAL HETEROCYCLIC FUSED AZEPINES USINGDIISOBUTYLALUMINUM HYDRIDE

Citation
H. Cho et al., REGIOSELECTIVE SYNTHESIS OF SEVERAL HETEROCYCLIC FUSED AZEPINES USINGDIISOBUTYLALUMINUM HYDRIDE, Heterocycles, 48(5), 1998, pp. 919-927
Citations number
11
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
0385-5414
Volume
48
Issue
5
Year of publication
1998
Pages
919 - 927
Database
ISI
SICI code
0385-5414(1998)48:5<919:RSOSHF>2.0.ZU;2-Q
Abstract
hieno[3,2-b]azepine,5,6,7,8-tetrahydro-1H-furo[3,- 2b]azepine, and 1,4 ,5,6,7,8-hexahydropyrrolo [3,2-b]azepine were synthesized by the ring expansion reaction of heterocyclic fused cyclohexanone oximes with dii sobutylaluminum hydride (DIBAH). The mechanism of the reaction was dif ferent from that of Beckmann rearrangement.