M. Okamoto et al., DIRECT SYNTHESIS OF ORGANOCHLOROSILANES BY THE REACTION OF METALLIC SILICON WITH HYDROGEN-CHLORIDE AND ALKENE ALKYNE/, Chemical communications, (12), 1998, pp. 1275-1276
Organosilicon compounds were directly synthesized from metallic silico
n, alkene/alkyne and HCl, EtHSiCl2 being obtained with 47% selectivity
from Si, C2H4 and HCl ae 513 K, and CH2=CHSiHCl2 and EtHSiCl2 with 39
smd 23% selectivity, respectively, when C2H2 was used in place of C2H
4.