A PLATINUM(II) COMPLEX CONTAINING CARBON-BONDED NITROMETHANE - [PT(CH2NO2)(2,2' 6',2''-TERPYRIDINE)](+)/

Authors
Citation
M. Akiba et Y. Sasaki, A PLATINUM(II) COMPLEX CONTAINING CARBON-BONDED NITROMETHANE - [PT(CH2NO2)(2,2' 6',2''-TERPYRIDINE)](+)/, INORGANIC CHEMISTRY COMMUNICATIONS, 1(2), 1998, pp. 61-63
Citations number
32
Language
INGLESE
art.tipo
Article
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
1387-7003
Volume
1
Issue
2
Year of publication
1998
Pages
61 - 63
Database
ISI
SICI code
1387-7003(1998)1:2<61:APCCCN>2.0.ZU;2-S
Abstract
X-ray structural analysis disclosed a carbon-bonded nitromethyl platin um(II) complex, (CH2NO2)(terpy)](+)(terpy=2,2':6',2'-terpyridine). The perchlorate salt was readily obtained by adding HClO4 to the nitromet hane solution of [Pt(OH)(terpy)](+). The emission spectra of the two s alts, perchlorate and tetraphenylborate, are significantly different, suggesting a different extent of the intermolecular interaction betwee n them. (C) 1998 Elsevier Science S.A.